You should say a beracha rishona before eating even the smallest amount of food. A beracha achrona, on the other hand, is not recited unless you eat a minimum of a kzayis of solid food or a rviyis of liquid.
http://brochot.tripod.com/foods/#top
Check out the berachot for common foods by clicking on the above link. You will even find the beracha for grapefruit juice by clicking on the letter g.
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